More on Stable Oxygen Isotopes
/by Carol Hasenberg
The geochemistry of rocks is a study that brings many great tools to the geologist’s tool chest. In the last article from October 2020, “Oxygen Isotope Analysis in Paleoclimatology,” I addressed an aspect of the geochemistry of the ocean and meteoric water on earth (meteoric water being rainwater, snow, water vapor in clouds, etc.) in the form of oxygen isotope distribution. This is a sort of shell game using stable isotopes of oxygen and how they are preferentially distributed in the waters of the earth. I will in this article explore the distribution of oxygen isotopes in rocks of the earth. These types of analyses are commonly used in many aspects of geological research and the reader will undoubtedly run across them in academic papers.
This article is not intended as a mathematical derivation of the equations used in isotope fractionation studies. (Recall that in the October 2020 article the term fractionation was described as a process of concentrating certain types of matter, in this case isotopes, in response to a phase change.) Instead, I will discuss in qualitative terms the principals that dictate how stable isotopes of oxygen distribute themselves in the rocks of the earth, and the resulting ranges of the isotopic ratios one expects to find in the rocks of the world.
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